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Removal of SO

Xiaolei LI, Chunying ZHU, Youguang MA

《化学科学与工程前沿(英文)》 2013年 第7卷 第2期   页码 185-191 doi: 10.1007/s11705-013-1326-5

摘要: In this work, the removal of SO from gas mixture with air and SO by ammonium bicarbonate aqueous solution as absorbent was investigated experimentally in a bubble column reactor. The effects of the concentration of ammonium bicarbonate, the SO inlet concentration of gas phase and the gas flow rate on the removal rate of SO were studied. The results showed that the higher the SO inlet concentration and the gas flow rate, the shorter the lasting time of SO completely removed in gas outlet, and then the faster the decrease in the removal rate of SO . The lasting time of SO completely removed in gas outlet increased with increasing ammonium bicarbonate concentration. During the process of SO absorption, there was a critical pH of solution. When the solution pH was less than the critical pH, it would sharply fall, resulting in a rapid decrease of the SO removal rate. A theoretical model for predicting the SO removal rate has been developed by taking the chemical enhancement and the sulfite concentration in the liquid phase into account simultaneously.

关键词: SO2 removal     bubble column reactor     removal rate     ammonium bicarbonate     absorbent    

The removal of trimethoprim and sulfamethoxazole by a high infiltration rate artificial composite soil

Qinqin Liu,Miao Li,Fawang Zhang,Hechun Yu,Quan Zhang,Xiang Liu

《环境科学与工程前沿(英文)》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0920-z

摘要: Artificial composite soil treatment system with the high infiltration rate (1.394 m·d ) had a good removal efficiency of TMP (80%–90%) and SMX (60%–70%). The removal mechanism of TMP and SMX was mainly sorption and was related with hydrogeochemical process. Sulfamethoxzole (SMX) and trimethoprim (TMP), two combined-using sulfonamide antibiotics, have gained increasing attention in the surface water, groundwater and the drinking water because of the ecological risk. The removal of TMP and SMX by artificial composite soil treatment system (ACST) with different infiltration rates was systematically investigated using K , Na , Ca , Mg hydrogeochemical indexes. Batch experiments showed that the sorption onto the low-cost and commercially available clay ceramsites was effective for the removal of SMX and TMP from water. The column with more silty clay at high infiltration rate (1.394 m·d ) had removal rates of 80% to 90% for TMP and 60% to 70% for SMX. High SMX and TMP removal rates had a higher effluent concentration of K , Ca and Mg and had a lower effluent Na concentration. Removal was strongly related to sorption. The results showed that the removal of SMX and TMP was related to hydrogeochemical processes. In this study, ACST is determined to be applicable to the drinking water plants.

关键词: Trimethoprim     Sulfamethoxazole     Artificial composite soil treatment     Hydrogeochemical processes     Ion exchange    

Effect of short-term atrazine addition on the performance of an anaerobic/anoxic/oxic process

Changyong WU, Xiaoling LI, Zhiqiang CHEN, Yongzhen PENG,

《环境科学与工程前沿(英文)》 2010年 第4卷 第2期   页码 150-156 doi: 10.1007/s11783-010-0020-9

摘要: In this study, an anaerobic/anoxic/oxic (AO) wastewater treatment process was implemented to treat domestic wastewater with short-term atrazine addition. The results provided an evaluation on the effects of an accidental pollution on the operation of a wastewater treatment plant (WWTP) in relation to Chemical Oxygen Demand (COD) and biological nutrient removal. Domestic wastewater with atrazine addition in 3 continuous days was treated when steady biological nutrient removal was achieved in the AO process. The concentrations of atrazine were 15, 10, and 5mg·L on days 1, 2 and 3, respectively. The results showed that atrazine addition did not affect the removal of COD. The specific NH NO reduction rate decreased slightly due to the short-term atrazine addition. However, it did not affect the nitrogen removal due to the high nitrification and denitrification capacity of the system. Total nitrogen (TN) removal was steady, and more than 70% was removed during the period studied. The phosphorus removal rate was not affected by the short-term addition of atrazine under the applied experimental conditions. However, more poly-hydroxy-alkanoate (PHA) was generated and utilized during atrazine addition. The results of the oxygen uptake rate (OUR) showed that the respiration of nitrifiers decreased significantly, while the activity of carbon utilizers had no obvious change with the atrazine addition. Atrazine was not removed with the AO process, even via absorption by the activated sludge in the process of the short-term addition of atrazine.

关键词: biological nutrient removal     atrazine     anaerobic/anoxic/oxic (A2O) process     oxygen demand removal     oxygen uptake rate (OUR)    

Arsenic (V) removal from groundwater by GE-HL nanofiltration membrane: effects of arsenic concentration

Xiaowei WANG, Wenjun LIU, Weifang MA, Desheng LI,

《环境科学与工程前沿(英文)》 2009年 第3卷 第4期   页码 428-433 doi: 10.1007/s11783-009-0146-9

摘要: A laboratory-scale investigation was performed to study arsenic (As (V)) removal by negatively charged GE-HL nanofiltration (NF) membrane in simulated drinking water. Effects of As (V) concentration (0–200μg·L), pH, and co-ions and counter-ions were investigated. The NF membrane presented good stability, and the rejection rates exceeded 90%. The rejection rates of As (V) decreased with the increase of As (V) concentration, while it increased with the increase of pH (reached 96% at pH 6.75). Moreover, a negative relationship was observed between the co-existing ions of Cl, Na, SO, and Ca and the removal of As (V), in which bivalent ions presented more significant effects than monovalent ions.

关键词: nanofiltration (NF)     rejection rate     co-existing ion     co-ion     counter-ion    

Modification of the activated sludge model for chemical dosage

Shuai MA,Siyu ZENG,Xin DONG,Jining CHEN,Gustaf OLSSON

《环境科学与工程前沿(英文)》 2015年 第9卷 第4期   页码 694-701 doi: 10.1007/s11783-014-0732-3

摘要: Full-scale experiments have been carried out to adapt the activated sludge model ASM2d to include the influence of metal dosage (Fe and Al ) for phosphorus removal. Phosphorus removal rates, nitrification rates, as well as pH and sludge settling performance, were evaluated as functions of the metal dosages. Furthermore, models relating certain parameters to the dosage of chemicals have been derived. Corresponding parameters in the ASM2d and the secondary settler models, included in the Benchmark Simulation Model No 1 (BSM1), have been modified to take the metal influence into consideration. Based on the effluent limits and penalty policy of China, an equivalent evaluation method was derived for the total cost assessment. A large number of 300-day steady-state and 14-day open-loop dynamic simulations were performed to demonstrate the difference in behavior between the original and the modified BSM1. The results show that 1) both in low and high mole concentrations, Fe addition results in a higher phosphorus removal rate than Al ; 2) the sludge settling velocity will increase due to the metal addition; 3) the respiration rate of the activated sludge is decreased more by the dosage of Al than Fe ; 4) the inhibition of Al on the nitrification rate is stronger than that of Fe ; 5) the total operating cost will reach the minimum point for smaller dosages of Fe , but always increase with Al addition.

关键词: chemical precipitation     benchmark simulation model     phosphorus removal     respiratory rate     sludge settling     activated sludge model    

Ultrasonic assisted EDM: Effect of the workpiece vibration in the machining characteristics of FW4 Welded Metal

Mohammadreza SHABGARD, Hamed KAKOLVAND, Mirsadegh SEYEDZAVVAR, Ramin Mohammadpour SHOTORBANI

《机械工程前沿(英文)》 2011年 第6卷 第4期   页码 419-428 doi: 10.1007/s11465-011-0246-7

摘要:

This paper presents the results of experimental studies carried out to conduct a comprehensive investigation on the influence of ultrasonic vibration of workpiece on the characteristics of Electrical Discharge Machining (EDM) process of FW4 Welding Metal in comparison with the conventional EDM process. The studied process characteristics included the material removal rate (MRR), tool wear ratio (TWR), and surface roughness (Ra and Rmax) of the workpiece after the EDM and ultrasonic assisted EDM (US-EDM) processes. The experiments performed under the designed full factorial procedure and the considered EDM input parameters included pulse on-time and pulse current. The experimental results show that in short pulse on-times, material removal rate in the US-EDM process is approximately quadruple than that of the EDM process. On the contrary, in the long pulse on-times, ultrasonic vibration of work??piece leads to the reduction in the MRR. On the other hand, in short pulse on-times, the TWR in the US-EDM process is lower than that of in the EDM process, and this condition reverses with increase in the pulse on-time. Furthermore, the surface roughness of the workpiece machined by EDM process is slightly lower than that of applied to the US-EDM process.

关键词: electrical discharge machining (EDM)     material removal rate (MRR)     tool wear ratio (TWR)     surface roughness    

The combined effects of biomass and temperature on maximum specific ammonia oxidation rate in domestic

《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1411-9

摘要:

• Actual SAORs was determined using MLVSS and temperature.

关键词: Specific ammonia oxidation rate     Sequencing batch reactor     Biomass     Temperature coefficient     Model simulation    

Use of float consumption rate in resource leveling of construction projects

Atilla DAMCI, Gul POLAT, Firat Dogu AKIN, Harun TURKOGLU

《工程管理前沿(英文)》 2022年 第9卷 第1期   页码 135-147 doi: 10.1007/s42524-020-0118-0

摘要: The management of resources has been claimed to be as important as scheduling methods. Inefficiency in managing resources may bring about severe delays and cost overruns caused by resource shortages in some cases and/or idle resources in others. Therefore, resources should be utilized efficiently to prevent project failures. Resource leveling is one of the approaches that are used for the management of resources. It aims to minimize fluctuations, peaks, and valleys in resource utilization without changing the completion time of a project and the number of resources required. Although the main principle behind traditional resource leveling is achieving an even flow of resources while the original project duration remains unchanged, the literature supports the need to develop an efficient model that discriminates among the activities that are selected for participation in resource leveling. For this purpose, this study has developed a model that considers the float consumption rates of activities in resource leveling. The float consumption rate is the percentage that is set to determine the maximum amount of float which will be consumed to shift the start time of the activity. The proposed model allows a scheduler to assign float consumption rates to each activity that can be used during the resource leveling procedure. When the required information is inputted, the proposed model automatically changes the required daily resources as it shifts the noncritical activities along their available total float times. The proposed model is expected to minimize the likelihood of severe delays and cost overruns. The model is demonstrated by constructing a network and its resource utilization histograms.

关键词: resource management     resource leveling     float consumption rate     scheduling    

Effect of loading rate on shear strength parameters of mechanically and biologically treated waste

《环境科学与工程前沿(英文)》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1595-7

摘要:

● Mechanical behavior of MBT waste affected by loading rate was investigated.

关键词: Mechanically and biologically treated waste     Landfill     Triaxial test     Loading rate     Axial strain     Shear strength parameter    

Size-controllable synthesis of monodispersed nitrogen-doped carbon nanospheres from polydopamine for high-rate

《化学科学与工程前沿(英文)》 2023年 第17卷 第11期   页码 1788-1800 doi: 10.1007/s11705-023-2326-8

摘要: Monodispersed nitrogen-doped carbon nanospheres with tunable particle size (100–230 nm) were synthesized via self-polymerization of biochemical dopamine in the presence of hexamethylenetetramine as a buffer and F127 as a size controlling agent. Hexamethylenetetramine can mildly release NH3, which in turn initiates the polymerization reaction of dopamine. The carbon nanospheres obtained exhibited a significant energy storage capability of 265 F·g–1 at 0.5 A·g–1 and high-rate performance of 82% in 6 mol·L–1 KOH (20 A·g–1), which could be attributed to the presence of abundant micro-mesoporous structure, doped nitrogen functional groups and the small particle size. Moreover, the fabricated symmetric supercapacitor device displayed a high stability of 94% after 5000 cycles, revealing the considerable potential of carbon nanospheres as electrode materials for energy storage.

关键词: carbon nanospheres     size-controlled     nitrogen-doped     high-rate     supercapacitors    

Improved rate-based modeling of carbon dioxide absorption with aqueous monoethanolamine solution

Stefania MOIOLI, Laura A. PELLEGRINI, Simone GAMBA, Ben LI

《化学科学与工程前沿(英文)》 2014年 第8卷 第1期   页码 123-131 doi: 10.1007/s11705-014-1415-0

摘要: This paper focuses on modeling and simulation of a post-combustion carbon dioxide capture in a coal-fired power plant by chemical absorption using monoethanolamine. The aim is to obtain a reliable tool for process simulation: a customized rate-based model has been developed and implemented in the ASPEN Plus software, along with regressed parameters for the Electrolyte-NRTL model worked out in a previous research. The model is validated by comparison with experimental data of a pilot plant and can provide simulation results very close to experimental data.

关键词: Absorption     carbon dioxide capture     rate-based model     monoethanolamine scrubbing    

Economic Growth Model Based on Six Basic Factors of Production—Xu Growth Rate Equation

Shou-bo Xu,Zong-yuan Huang

《工程管理前沿(英文)》 2014年 第1卷 第2期   页码 160-175 doi: 10.15302/J-FEM-2014024

摘要: This paper proposes an economic growth model based on the Six Basic Factors of Production and Xu Growth Rate Equation for the first time, which fills-in the deficits of the New Classical Economic Growth Model based on the Solow Model. The empirical analysis indicates that over the past three decades, the consumption of six basic factors of production had complicated relations with economic growth. In some years, the consumption rate of the basic factors of production was meager, but the economy witnessed relatively rocketing growth rate; in some years, the factors of production consumption rate was very high, but the economy growth rate slowed down. In general, economy grows at the expenses of huge consumption of four factors. There is an obvious characteristic of huge input and low efficiency. The average contribution rate of technological advance peaks in the middle, while it drops down at two ends. Noticeably, since 2004, the technology contribution rate generally shows a downward trend, reasons of which should be explored systematically in aspects like economic policy and industry structure with a view to boost further transformation of the macro-economy scientific growth model.

关键词: six basic factors of production     economic growth model     Xu Growth Rate Equation    

Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

《环境科学与工程前沿(英文)》 2009年 第3卷 第3期   页码 313-319 doi: 10.1007/s11783-009-0025-4

摘要: This investigation was carried out to establish a new domestic landfill gas (LFG) generation rate model that takes into account the impact of leachate recirculation. The first-order kinetics and two-stage reaction (FKTSR) model of the LFG generation rate includes mechanisms of the nutrient balance for biochemical reaction in two main stages. In this study, the FKTSR model was modified by the introduction of the outflow function and the organic acid conversion coefficient in order to represent the in-situ condition of nutrient loss through leachate. Laboratory experiments were carried out to simulate the impact of leachate recirculation and verify the modified FKTSR model. The model calibration was then calculated by using the experimental data. The results suggested that the new model was in line with the experimental data. The main parameters of the modified FKTSR model, including the LFG production potential (), the reaction rate constant in the first stage (), and the reaction rate constant in the second stage () of 64.746 L, 0.202 d, and 0.338 d, respectively, were comparable to the old ones of 42.069 L, 0.231 d, and 0.231 d. The new model is better able to explain the mechanisms involved in LFG generation.

关键词: landfill gas (LFG)     generation rate model     first-order kinetics     two-stage reaction     outflow function    

arrays as promising current collectors for constructing solid-state supercapacitors with ultrahigh rate

Huaping Zhao, Long Liu, Yaoguo Fang, Ranjith Vellacheri, Yong Lei

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 339-345 doi: 10.1007/s11705-018-1699-6

摘要:

In this work, nickel nanopore arrays with a highly-oriented nanoporous structure inherited from porous alumina membranes were used as nanostructured current collectors for constructing ultrahigh rate solid-state supercapacitors. A thin layer of poly(3,4-ethylenedioxythiophene) (PEDOT) as electroactive materials was conformally coated onto nickel nanopores to form heterostructured electrodes. The as-prepared electrodes have a large specific surface area to ensure a high capacity, and the highly-oriented nanoporous structure of nickel nanopores reduces the ion transport resistance, allowing the ions in the solid-state electrolytes to quickly access the PEDOT surface during the fast charge-discharge process. As a result, the assembled solid-state supercapacitor in a symmetric configuration exhibits an ideal capacitive behavior and a superior rate capability even at an ultrahigh scan rate of 50 V·s1.

关键词: supercapacitor     ultrahigh rate     metallic nanopore arrays     current collectors     PEDOT    

Effect of dilution rate on dynamic and steady-state biofilm characteristics during phenol biodegradation

Veena Bangalore Rangappa, Vidya Shetty Kodialbail, Saidutta Malur Bharthaiyengar

《环境科学与工程前沿(英文)》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0863-9

摘要: Continuous pulsed plate bioreactor (PPBR) was used for phenol biodegradation. cells immobilized on granular activated carbon was used. Dynamic and steady state biofilm characteristics depend on dilution rate (DR). Lower DR favour phenol degradation and uniform, thick biofilm formation. Exo polymeric substance production in biofilm are favoured at lower dilution rates. Pulsed plate bioreactor (PPBR) is a biofilm reactor which has been proven to be very efficient in phenol biodegradation. The present paper reports the studies on the effect of dilution rate on the physical, chemical and morphological characteristics of biofilms formed by the cells of Pseudomonas desmolyticum on granular activated carbon (GAC) in PPBR during biodegradation of phenol. The percentage degradation of phenol decreased from 99% to 73% with an increase in dilution rate from 0.33 h?1 to 0.99 h?1 showing that residence time in the reactor governs the phenol removal efficiency rather than the external mass transfer limitations. Lower dilution rates favor higher production of biomass, extracellular polymeric substances (EPS) as well as the protein, carbohydrate and humic substances content of EPS. Increase in dilution rate leads to decrease in biofilm thickness, biofilm dry density, and attached dry biomass, transforming the biofilm from dense, smooth compact structure to a rough and patchy structure. Thus, the performance of PPBR in terms of dynamic and steady-state biofilm characteristics associated with phenol biodegradation is a strong function of dilution rate. Operation of PPBR at lower dilution rates is recommended for continuous biologic treatment of wastewaters for phenol removal.

关键词: Biofilm     Exopolymeric substances     Phenol     Dilution rate     Pulsed plate bioreactor    

标题 作者 时间 类型 操作

Removal of SO

Xiaolei LI, Chunying ZHU, Youguang MA

期刊论文

The removal of trimethoprim and sulfamethoxazole by a high infiltration rate artificial composite soil

Qinqin Liu,Miao Li,Fawang Zhang,Hechun Yu,Quan Zhang,Xiang Liu

期刊论文

Effect of short-term atrazine addition on the performance of an anaerobic/anoxic/oxic process

Changyong WU, Xiaoling LI, Zhiqiang CHEN, Yongzhen PENG,

期刊论文

Arsenic (V) removal from groundwater by GE-HL nanofiltration membrane: effects of arsenic concentration

Xiaowei WANG, Wenjun LIU, Weifang MA, Desheng LI,

期刊论文

Modification of the activated sludge model for chemical dosage

Shuai MA,Siyu ZENG,Xin DONG,Jining CHEN,Gustaf OLSSON

期刊论文

Ultrasonic assisted EDM: Effect of the workpiece vibration in the machining characteristics of FW4 Welded Metal

Mohammadreza SHABGARD, Hamed KAKOLVAND, Mirsadegh SEYEDZAVVAR, Ramin Mohammadpour SHOTORBANI

期刊论文

The combined effects of biomass and temperature on maximum specific ammonia oxidation rate in domestic

期刊论文

Use of float consumption rate in resource leveling of construction projects

Atilla DAMCI, Gul POLAT, Firat Dogu AKIN, Harun TURKOGLU

期刊论文

Effect of loading rate on shear strength parameters of mechanically and biologically treated waste

期刊论文

Size-controllable synthesis of monodispersed nitrogen-doped carbon nanospheres from polydopamine for high-rate

期刊论文

Improved rate-based modeling of carbon dioxide absorption with aqueous monoethanolamine solution

Stefania MOIOLI, Laura A. PELLEGRINI, Simone GAMBA, Ben LI

期刊论文

Economic Growth Model Based on Six Basic Factors of Production—Xu Growth Rate Equation

Shou-bo Xu,Zong-yuan Huang

期刊论文

Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

期刊论文

arrays as promising current collectors for constructing solid-state supercapacitors with ultrahigh rate

Huaping Zhao, Long Liu, Yaoguo Fang, Ranjith Vellacheri, Yong Lei

期刊论文

Effect of dilution rate on dynamic and steady-state biofilm characteristics during phenol biodegradation

Veena Bangalore Rangappa, Vidya Shetty Kodialbail, Saidutta Malur Bharthaiyengar

期刊论文